Corrosion Inhibition of Low Carbon Steel in Hydrochloric Acid By Cardaria Draba Leaves Extracts

The corrosion inhibition of mild carbon steel in solution was studied in presence of Cardaria Draba leaf extracts and his absence; it is a nontoxic and environmentally friendly inhibitor. The study was at different temperatures and different concentrations of extract using weight loss technique. the inhibition efficiency increases with increase in the concentration of the extract also with rising in temperature, where the maximum inhibition is around (94.3%). the results obtained showed that extract act as an inhibitor for mild carbon steel in and reduces the corrosion rate. the adsorption of Cardaria Draba leaf extracts was found to follow Langmuir adsorption isotherm. The values of the free energy of adsorption were more than (-20kJ/mol), which is indicative of a mixed mode of chemical and physical adsorption, but chemical adsorption is the predominant mode of adsorption. Corrosive, green inhibitors, mild carbon steel, adsorption.


Introduction 1.
Mild carbon steel uses in numerous industrial establishments due to good tensile strength, easy availability, low-cost and many other desirable characteristics . mild steel corrosive in acid medium causes significant damage, and acidic solutions are widely using to remove unwanted crust and rusting in a lot of industrial procedure, the major trouble with the use steel are degradation by acidic solutions . the used of corrosive inhibitors are one of the more effective measures to protect steel surfaces from corrosion in acidic mediums . the inhibitory activity rely on concentrating of the inhibitor itself and type of alloy studied, most inorganic-organic and inhibitors are too expensive, environmentally friendly and toxic, as a result of increased environmental awareness and the negative impact of some chemicals, an alternative should be sought to replace organic and inorganic Mild steel specimen are using for this study ,and were a local source , it have the next chemical installation; C (0.0182%), Si (0.0176%), Cu (0.0169%), Mn (0.394%), P (less than 0.0005%), S (0.0330%), Cr (0.0333%), Mo (less than 0.001%), Ni (less than 0.001%) ,Ti (0.002%), Al (0.0491%), As (less than 0.0005%), B (less than 0.0005%), Co (less than 0.001%), Ca (more than 0.008%), Nb (less than 0.001%), Sn (less than 0.001%), V (0.0005%), Zr (0.0078%) and the remainder is Fe, each sample had its dimensions ( ) and the surface area is about the samples were first annealed in the electric oven for one hour at a temperature of cooled to room temperature , these samples are rubbed using emery paper and gradually (60, 80, 100, 320, 400), thereafter washes with faucet water and then with filtered water and drying up by tissue paper, immersing at benzene, acetone then drying once more, lastly keep in the desiccator until use, the weight of the samples is measured using a Four mattresses electronic balance, the dimension are measuring accurately using a special electronic Vernier , the steel samples are immersion in a beaker container containing test solution (consists of and inhibitor concentration) at the temperature for ( ), after immersion is re-weight, and the variance at the weight of steel samples before exposure and after him is taken for different corrosion solutions, a weight loss determines in the presence of inhibitor and his absence ( and the inhibitor concentration used ( ) each test is repeated twice and takes mean values .

preparation of Cardaria draba leaf extractor:
Cardaria draba leaf ( ), are easily available, inexpensive, and plants common in Diyala province / iraq, the leaf are collecting and dries by the shade, grind using the blender and turn into fine powdering, Preparing the extractor by escalation from powdered dry at of for keep it night long, a product is filtered and the amount of leachate it is with limit the using Himself acid as an solution to corrosion and parts with the volumes of ( )/Liter of

Prepare of the corrosive medium:
The corrosive medium was Its molecular weight Prepared from 36% analytical grad supplied by Central Drug House ( ), dilutes the acid with filtered water to prepared a hydrochloric acid solution, for all group of prepared experiments using an solutions to avoidance of polluting effects.

Weight loss technique:
Corrosive rates of mild carbon steel were determined with the presence of several concentrations of the extract and his absence in the acid solution by weight loss method at temperatures of various, of the following equation the corrosion rate value calculates: Where/ A are a surface area in are the weight wastage with (g), is time of exposure in (day).
Using the following neutralization, the ratio of inhibitor efficiency calculates From the corrosion rate: Where/ ( , ) is the corrosive rates in the presence and absence of different concentrations of inhibitor respectively.

( ) Scanning Electron Microscope:
The ( ) ( ) it has been using to study morphology of mild carbon steel surface with the presence of Cardaria draba leaf extractor and his absence during the exposure period in at the temperature of 3. Results and discussion:

Weight loss measurements
The results listing in table (1)    Where is the absolute temperature, A -frequency factor, -universal gas constant

) Activation parameters for corrosion inhibition of mild steel surface in
in presence and absence of (CDL) extract as the corrosive inhibitor.

Effect of inhibitor concentration
When used plant extract to inhibits corrosive of mild steel, there would be adsorption of ingredients the extract on the metal surface, leading to a larger surface coverage as a first step of the inhibition mechanism. Surface coverage data defined as part of the surface of the steel that was covered with an inhibitor are very useful during the discussion of adsorption properties, assuming a directly relation between and surface coverage, the expression of surface coverage it can assessed . Suggested was two model to study the adsorption kinetics of on the steel surface, Langmuir adsorption isotherm Eq. (5) and Freundlich adsorption isotherm Eq. (6).
Where is the inhibitor efficiency, -surface coverage, C -inhibitor concentration, nconstant and -equilibrium adsorption constant. Equations (5), (6) it be plotted as explain in figures (5,6). by means of equation (7) can be estimated the standard free energy

studies
The main step in inhibiting corrosion is the adsorption of the inhibitors on the metal surface to be protected. FTIR analysis is therefore performed to obtain some clarification  5. The adsorption of extract molecules on surface of mild steel is due to chemical and physical adsorption (comprehensive adsorption) but chemical adsorption is the predominant mode of adsorption.
6. In the presence of a CDL extract, the activation energy decreases in the corrosion operation.
7. spectra clearly is showed the phytochemicals adsorption on mild carbon steel surface.
8. morphology revealed that inhibition of corrosion was due to adsorption of molecules on the alloy surface.
9. It is preferable to use an acceptable plant extract for a non-toxic environment always on organic inhibitors.