Effect of Strontium on the Structural, Optical, and Magnetic Properties of Bi(1-x)SrxFeO3

Authors

  • Khalid H. Jebur Ministry of Oil, Baghdad ‏Oil Training Institute, Baghdad, Iraq

DOI:

https://doi.org/10.52716/jprs.v15i1.898

Keywords:

solid-state reaction, Bi(1-x)SrxFeO3‎, magnetic‎ properties.

Abstract

The composite Bi(1-x) SrxFeO3 (x = 0.0, 0.2, 0.4, 0.6, 0.8) was produced via solid-state reaction technique at 850 °C, in order to evaluate how strontium affects the structure. X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive ‎X-ray spectroscopy (EDX), magnetic analysis (VSM), and band gap energy measurements ‎were performed by UV- visible spectroscopy. ‏The results obtained are the formation of ‎crystalline materials of rhombohedral surfaces and change to the pseudocubic phase ‎at x = 0.4. The particle size declines ‎from 36.5 nm up to 17 nm for the pure sample in BSFO. The strontium Sr+2   caused an increase in   ‎Remnant magnetization (Mr) and coercive field (Hc), which lead to the magnetization ‎development of BiFeO3, UV- visible spectroscopy used to‏ ‏calculate the direct optical ‎band gap of all samples had its value on the order of 2.4 to 2.9 eV.

References

S. Sindhu, and M. R. Anantharaman, “Preparation and Characterization of Spinel Ferrites –‎Their Incorporation in Rubber Matrix and Evaluation of Properties,” PhD diss., Cochin University of Science and Technology, 2001‎. http://dyuthi.cusat.ac.in/purl/1001

D. Dimos, and C. Mueller, “Perovskite Thin Films For High-Frequency Capacitor Applications”, ‎ Annual Review of Materials Research, vol. 28, pp. 397-419, 1998.‎ https://doi.org/10.1146/annurev.matsci.28.1.397

A. I. Kingon, S. K. Streiffer, C. Basceri, and S. R. Summerfelt, “High-Permittivity Perovskite Thin Films for Dynamic Random-Access Memories"‎, MRS Bulletin, ‏‎ vol. 21, no. 7, pp. 46-52, 1996.‎ https://doi.org/10.1557/S0883769400035910

H. Obayashi, Y. Sakurai, and T. Gejo, “‎Perovskite-type oxides as ethanol sensors”, ‎ Journal of Solid State Chemistry, ‎‎vol. 17, no. 3, pp. 299-303, 1976. https://doi.org/10.1016/0022-4596(76)90135-3

T. Rogers-Hayden and N. Pidgeon, “Moving engagemen‏,‎‏ ‏upstream‏”‏‎ ‎Nanotechnologies and the royal society and royal academy of ‎engineering’s inquiry,” Public Underst. Sci., vol. 16, no. 3, pp. 345–‎‎364, Jul. 2007. ‎ https://doi.org/10.1177/0963662506076141

J. Wu, S. Mao, Z.-Guang Ye, Z. Xiea and L. ‎Zhenga‏‎,” Room-‎temperature ferromagnetic/ferroelectric BiFeO3 synthesized by ‎a self-‎catalyzed fast reaction process”,‎‏‎ Journal of Materials Chemistry‏, vol. 20, no. 48, pp. 6512-6516, 2012‏.‏ http://dx.doi.org/10.1039/C0JM00729C

S. Gulah and L. Masoudi, “Study of the structural, electronic ‎and magnetic properties of BiFeO3 perovskite”, MA thesis, Al-Arabi ‎Al-Tepsi University‎.

Y. F. Popov, A. K. Zvezdin, G. P. Vorob'Ev, A. M. Kadomtseva‎, V. A. Murashev, D. N. Rakov, D. Parsons, “linear magnetoelectric effect and phase transitions in bismuth ferrite, BiFeO3” ‏‎, JETP Letters, vol 57, no. 1, pp. 69-73, 1993.

N. A. Hill, “Why Are There so Few Magnetic Ferroelectrics?”, The Journal of Physical Chemistry B, vol. 104, no. 29, pp. 6694-6709, 2000‎‎. https://doi.org/10.1021/jp000114x

M. Amin, “Exploring the Multifunctional Properties of BiFeO3 -Based Multiferroics”, Department of Physics, University of the Punjab, Lahore, 54590 ‎‎(Pakistan), 2018. ‎

W. Nan, L. Xudong, L. Han, Z. Zhiqiang, R. Zhang, H. Olin, and Y. Yang‎,‎ “Structure, Performance, and ‎Application of BiFeO3 Nanomaterials”, Nano-Micro Letters, vol. 12, article no. 81, 2020. ‎ https://doi.org/10.1007/s40820-020-00420-6

V. A. Khomchenko, D. A. Kiselev, J. M. Vieira, A. L. Kholkin, M. A. Sá, and Y. G. Pogorelov, “‎Synthesis and multiferroic properties of Bi0.8A0.2FeO3 (A=Ca, Sr, Pb) ceramics”, Appl. Phys. Lett., vol. 90, no. 24, p. 242901, 2007. https://doi.org/10.1063/1.2747665

A. Z. Simões, F. G. Garcia, and C. dos Santos Riccardi, “Rietveld ‎analysys and electrical properties of lanthanum ‎doped BiFeO3 ‎ceramics”, ‎‏ ‏Materials Chemistry and Physics, vol. ‎‎116, no. 2–3, pp. 305-309, 2009. https://doi.org/10.1016/j.matchemphys.2009.04.036

M. A. Awad, “Study the structural electrical and magnetic properties of M-type nano hexaferrites prepared via chemical route”, the Degree of master of the University of Kirkuk, 2021.

S. Palomares-Sánchez, S. Ponce-Castañeda, F. Ruiz, M. Mirabal-García, J. R. Martínez, and S. Díaz-Castañón, “Structural and magnetic characterization of (Ba,Sr)-hexaferrite powders,” Rev. Metal., vol. 35, no. 3, pp. 143–147, 1999. https://doi.org/10.3989/revmetalm.1999.v35.i3.617

M. Troemel, “Institute für Anorganische Chemie der Johann Wolfgang”, ICDD Grant-in-Aid Recipients, Goethe-Universität, Frankfurt, ‎Germany, 2014.

K. Uchino, S. Nomura, L. E. Cross, R. E. Newnham, and S. J. Jang, “Electrostrictive effect in perovskites and its transducer applications”, Journal ‎of Materials Science, vol. 16, pp. 569–578, 1981. ‎ https://doi.org/10.1007/BF00552193

M. Z. Shoushtari, A. Emami, and S. E. M. Ghahfarokhi, “‎Effect of bismuth doping ‎on the structural and magnetic ‎properties of ‎zinc-ferrite nanoparticles prepared by a ‎microwave ‎combustion ‎method", Journal of Magnetism and Magnetic Materials, ‎‎vol. 419, pp. 572-‎‎‎579, 2016. https://doi.org/10.1016/j.jmmm.2016.06.080

Downloads

Published

2025-03-21

How to Cite

(1)
Jebur, K. H. . Effect of Strontium on the Structural, Optical, and Magnetic Properties of Bi(1-x)SrxFeO3. Journal of Petroleum Research and Studies 2025, 15, 197-210.