Synthesized and Characterization TiO2-AlLiH4 Nanostructure for Photocatalytic Activity Application for Removal the Residue of Hydrocarbons in Environment

المؤلفون

  • معتصم الصالح UPSI university, Faculty of Science and Mathamtic, Malaysia
  • رياض عبد The General Directorate of Education, Thi-Qar Governorate, Iraq. UPSI university, Faculty of Science, Biology Department.

DOI:

https://doi.org/10.52716/jprs.v12i1.602

الكلمات المفتاحية:

Nanocomposite, Hydrocarbons removal, Photocatalytic, TiO2 - AlLiH4

الملخص

يتضمن النهج الجديد استخدام تقنية sol-gel لتصنيع جسيمات نانوية لثاني أكسيد التيتانيوم لاجل التحلل  الضوئي   أنثراسين بنز اي والذي يعد  هيدروكربون بلوري عطري، كعينة تجريبية لبقايا الهيدروكربونات في بيئات قريبة من منشآت تكرير النفط وحقول النفط. تم تعديل فجوة الحزمة عن طريق تفاعل الحالة الصلبة مع مركبات اختزال هيدريد الألومنيوم الليثيوم.  تم قياس الخواص الضوئية باستخدام مقياس طيف ضوئي مرئي للأشعة فوق البنفسجية الامتصاصية ، و قياس فجوة الطاقة (على سبيل المثال)، ومعامل الامتصاص أظهر تفاعل TiO2 و TiO2- الحالة الصلبة انزياحًا أزرقًا واضحًا لفجوة الامتصاص التي كانت  ٢،٨ - ٢،٧-٢،٢٥-٢،٠ الكترون فولت عند درجة كلسنة ٥٠٠ درجة مئوية ثم رفعها إلى ٧٥٠ درجة مئوية على التوالي. تم التعرف على بنية مساحيق TiO2 النانوية المحضرة باستخدام XRD ، حيث اختلف توزيع حجم الجسيمات بشكل كبير مقارنة بالصيغة المتنبأ بها بالحجم البلوري  والتي كانت في توافق جيد مقارنة بنتائج ASTM ، وتم تمييز حجم الجسيمات وتوزيعها باستخدام (AFM) تم دراسة  الأشكال والتركيبات السطحية بأقطار الجسيمات النانوية (SEM). تم استخدام التحليل المجهري للأشعة السينية المشتتة للطاقة (EDX) لفحص التركيب الكيميائي للعينات بأكملها. باستخدام القياس الطيفي بالأشعة المرئية وفوق البنفسجية ، تم فحص استجابة التحفيز الضوئي. تأثير المحفز الضوئي على  انثراسين البنزين [أ] لملاحظة معدل تحلل الأنثراسين باستخدام المحفز TiO2- الحالة الصلبة (TiO2-NaBH4 (550.750)) و (TiO2-AlLiH4 (500.750 درجة مئوية). التأثير التحفيزي هو تأثير المحفز على المحفز باستخدام الوزن الثابت للعامل المحفز والبنز [أ] أنثراسين تم العثور على الوزن الأكثر فعالية (1 * 10-4 م).

المراجع

Patil SB, Basavarajappa PS, Ganganagappa N, Jyothi MS, Raghu AV, Reddy KR. Recent advances in non-metals-doped TiO2 nanostructured photocatalysts for visible-light-driven hydrogen production, CO2 reduction, and air purification. International Journal of Hydrogen Energy. 2019 May 21; 44(26):13022-39.

Etacheri V, Di Valentin C, Schneider J, Bahnemann D, Pillai SC. Visible-light activation of TiO2 photocatalysts: Advances in theory and experiments. Journal of Photochemistry and Photobiology C: Photochemistry Reviews. 2015 Dec 1;25:1-29.

Pelaez M, Nolan NT, Pillai SC, Seery MK, Falaras P, Kontos AG, Dunlop PS, Hamilton JW, Byrne JA, O'Shea K, Entezari MH. A review on the visible light active titanium dioxide photocatalysts for environmental applications. Applied Catalysis B: Environmental. 2012 Aug 21;125:331-49.

Yunus, N. N., F. Hamzah, M. S. So’Aib, and J. Krishnan. "Effect of catalyst loading on photocatalytic degradation of phenol by using N, S Co-doped TiO2." In IOP Conference Series: Materials Science and Engineering, vol. 206, no. 1, p. 012092. IOP Publishing, 2017.

Rajalakshmi K. Photocatalytic Reduction of Carbon dioxide in conjunction with the decomposition of water on oxide semiconductor surfaces. Indian Institute of Technology, Madras, India. 2011.

Zaker, Y., Hossain MA, M. Ali, M. S. Islam, and T. S. A. Islam. "Characterization of sand fractionated from Bijoypur soil, Bangladesh and its application as an adsorbent." Research Journal of Chemical Sciences ISSN 2231 (2013): 606X.

Liu, Jincheng, Hongwei Bai, Yinjie Wang, Zhaoyang Liu, Xiwang Zhang, and Darren Delai Sun. "Self‐assembling TiO2 nanorods on large graphene oxide sheets at a two‐phase interface and their anti‐recombination in photocatalytic applications." Advanced Functional Materials 20, no. 23 (2010): 4175-4181.

AlSalih, Moatasem, Syakirah Samsudin, and Siti Suri Arshad. "Synthesis, Properties and Application of Titanium Dioxide Doped with Nitrogen. Its Effectiveness on Photo Degradation Glutathione-S-Transferase (GST) enzymes Pupae Instar of Aedes aegypti." In Journal of Physics: Conference Series, vol. 1963, no. 1, p. 012131. IOP Publishing, 2021.

Ong, Wee-Jun, Lling-Lling Tan, Siang-Piao Chai, Siek-Ting Yong, and Abdul Rahman Mohamed. "Highly reactive {001} facets of TiO 2-based composites: synthesis, formation mechanism and characterization." Nanoscale 6, no. 4 (2014): 1946-2008.

Sudha, D., and P. Sivakumar. "Review on the photocatalytic activity of various composite catalysts." Chemical Engineering and Processing: Process Intensification 97 (2015): 112-133.

Zhang, Wei, Yong Tian, Haili He, Li Xu, Wei Li, and Dongyuan Zhao. "Recent advances in the synthesis of hierarchically mesoporous TiO2 materials for energy and environmental applications." National Science Review 7, no. 11 (2020): 1702-1725.

Al-Mamun, M. R., S. Kader, M. S. Islam, and M. Z. H. Khan. "Photocatalytic activity improvement and application of UV-TiO2 photocatalysis in textile wastewater treatment: A review." Journal of Environmental Chemical Engineering 7, no. 5 (2019): 103248..

Hao, Dandan, Yudi Yang, Bi Xu, and Zaisheng Cai. "Bifunctional fabric with photothermal effect and photocatalysis for highly efficient clean water generation." ACS Sustainable Chemistry & Engineering 6, no. 8 (2018): 10789-10797.

Yang, Jinhui, and Xiaogang Luo. "Ag-doped TiO2 immobilized cellulose-derived carbon beads: One-Pot preparation, photocatalytic degradation performance and mechanism of ceftriaxone sodium." Applied Surface Science 542 (2021): 148724.

Lee, Sang-Hwan, Won-Seok Lee, Chang-Ho Lee, and Jeong-Gyu Kim. "Degradation of phenanthrene and pyrene in rhizosphere of grasses and legumes." Journal of Hazardous Materials 153, no. 1-2 (2008): 892-898.

Rani, Manviri, and Uma Shanker. "Sunlight mediated improved photocatalytic degradation of carcinogenic benz [a] anthracene and benzo [a] pyrene by zinc oxide encapsulated hexacyanoferrate nanocomposite." Journal of Photochemistry and Photobiology A: Chemistry 381 (2019): 111861.

Guo, Jin, Xiuchu Liu, Xiaomei Zhang, Juan Wu, Chao Chai, Dong Ma, Qinghua Chen, Dan Xiang, and Wei Ge. "Immobilized lignin peroxidase on Fe3O4@ SiO2@ polydopamine nanoparticles for degradation of organic pollutants." International journal of biological macromolecules 138 (2019): 433-440.

Bagheri, Samira, Zul Adlan Mohd Hir, Amin Termeh Yousefi, and Sharifah Bee Abdul Hamid. "Progress on mesoporous titanium dioxide: synthesis, modification and applications." Microporous and Mesoporous Materials 218 (2015): 206-222.

Deng Y, Wei J, Sun Z, Zhao D. Large-pore ordered mesoporous materials templated from non-Pluronic amphiphilic block copolymers. Chemical Society Reviews. 2013;42(9):4054-70.

Kim, Ki-Hyun, Shamin Ara Jahan, Ehsanul Kabir, and Richard JC Brown. "A review of airborne polycyclic aromatic hydrocarbons (PAHs) and their human health effects." Environment international 60 (2013): 71-80. [24] WRITER HA. LEVELS OF POLYCYCLIC AROMATIC HYDROCARBON IN FRESHWATER FISH DRIED UNDER DIFFERENT DRYING REGIMES. 2021

Giri SK, Kumar A, Kumar A, Gulati S. Effects of Polycyclic Aromatic Hydrocarbons on Environment Health. ICRIET-2016; ISBN: 978-93-856181-6

Alegbeleye, Oluwadara Oluwaseun, Beatrice Oluwatoyin Opeolu, and Vanessa Angela Jackson. "Polycyclic aromatic hydrocarbons: a critical review of environmental occurrence and bioremediation." Environmental management 60, no. 4 (2017): 758-783.

Rabani, Mir Sajad, Aukib Habib, and Mahendra Kumar Gupta. "Polycyclic Aromatic Hydrocarbons: Toxic Effects and Their Bioremediation Strategies." In Bioremediation and Biotechnology, Vol 4, pp. 65-105. Springer, Cham, 2020.

Bäumler, Wolfgang. "Chemical hazard of tattoo colorants." La Presse Médicale 49, no. 4 (2020): 104046.

Neff, Jerry M., Scott A. Stout, and Donald G. Gunster. "Ecological risk assessment of polycyclic aromatic hydrocarbons in sediments: identifying sources and ecological hazard." Integrated Environmental Assessment and Management: An International Journal 1, no. 1 (2005): 22-33.

Hartwig, Andrea, ed. The MAK-Collection for Occupational Health and Safety: Part I: MAK Value Documentations, Volume 27. John Wiley & Sons, 2013.

Idowu, Oluyoye, Kirk T. Semple, Kavitha Ramadass, Wayne O'Connor, Phil Hansbro, and Palanisami Thavamani. "Beyond the obvious: Environmental health implications of polar polycyclic aromatic hydrocarbons." Environment international 123 (2019): 543-557.

Goldizen, Fiona C., Peter D. Sly, and Luke D. Knibbs. "Respiratory effects of air pollution on children." Pediatric pulmonology 51, no. 1 (2016): 94-108.

Mackie, Cameron J., Tao Chen, Alessandra Candian, Timothy J. Lee, and Alexander GGM Tielens. "Fully anharmonic infrared cascade spectra of polycyclic aromatic hydrocarbons." The Journal of chemical physics 149, no. 13 (2018): 134302.

Huang, Jianshe, Yang Liu, Haoqing Hou, and Tianyan You. "Simultaneous electrochemical determination of dopamine, uric acid and ascorbic acid using palladium nanoparticle-loaded carbon nanofibers modified electrode." Biosensors and Bioelectronics 24, no. 4 (2008): 632-637.

[[35] Ksibi, Mohamed, Sylvie Rossignol, Jean-Michel Tatibouët, and Christos Trapalis. "Synthesis and solid characterization of nitrogen and sulfur-doped TiO2 photocatalysts active under near visible light." Materials Letters 62, no. 26 (2008): 4204-4206.

Chen, Ying-Li, and Qian-Zhong Li. "Prediction of apoptosis protein subcellular location using improved hybrid approach and pseudo-amino acid composition." Journal of theoretical biology 248, no. 2 (2007): 377-381.

Shen, Jiandong, Shicheng Zhang, Jinjun Lian, Lingdong Kong, and Jianmin Chen. "Benz [a] anthracene heterogeneous photochemical reaction on the surface of TiO2 particles." Acta Physico-Chimica Sinica 23, no. 10 (2007): 1531-1536.

Boscher, Nicolas D., Claire J. Carmalt, Robert G. Palgrave, and Ivan P. Parkin. "Atmospheric pressure chemical vapour deposition of SnSe and SnSe2 thin films on glass." Thin solid films 516, no. 15 (2008): 4750-4757.

Qiu, Shipeng, and Samar J. Kalita. "Synthesis, processing and characterization of nanocrystalline titanium dioxide." Materials Science and Engineering: A 435 (2006): 327-332.

Odum, Jay R., Stephen R. McDow, and Richard M. Kamens. "Mechanistic and kinetic studies of the photodegradation of benz [a] anthracene in the presence of methoxyphenols." Environmental science & technology 28, no. 7 (1994): 1285-1290.

AlSalih Et Al, Moatasem. "Adjustment and Application of the Band Gap of Nano Titanium Dioxide: Its Usefulness on Photo degradation of Wastewater (phenol)." Egyptian Journal of Aquatic Biology and Fisheries 25, no. 3 (2021): 815-830.

Sims, P. "Epoxy derivatives of aromatic polycyclic hydrocarbons. The preparation of benz [a] anthracene 8, 9-oxide and 10, 11-dihydrobenz [a] anthracene 8, 9-oxide and their metabolism by rat liver preparations." Biochemical Journal 125, no. 1 (1971): 159-168.

Al Salih, Seenaa Wdaah, Moatasem Al Salih, and Syakirah Samsudin. "MODIFICATION OF THE BAND GAP OF NANO TITANIUM DIOXIDE, ITS APPLICATION AND EFFECTIVENESS ON PHOTO DEGRADATION OF ORGANIC POLLUTANTS.

التنزيلات

منشور

2022-03-20

كيفية الاقتباس

(1)
Al Salih, M. .; Abed, R. E. . Synthesized and Characterization TiO2-AlLiH4 Nanostructure for Photocatalytic Activity Application for Removal the Residue of Hydrocarbons in Environment . Journal of Petroleum Research and Studies 2022, 12, 267-283.