Isothermal adsorption models: mini-focused observations

كفاء خلف حمود

doi:10.52716/jprs.v13i1.613

المؤلفون

كفاء خلف حمود وزارة العلوم والتكنولوجيا

DOI:

https://doi.org/10.52716/jprs.v13i1.613

الكلمات المفتاحية:

adsorption, isotherm model, Freundlich, Langmuir, Temkin, R2.

الملخص

Adsorption is kinetically time-dependence controlled retention/ release mobility as a natural phenomenon in base and applicable in industry or in science. It is well-studied and modulated by known Langmuir, Temkin, Freundlich, and other models to describe how it occurred and explains kinetic- thermodynamic material behaviour.

Linear and/ or non- linear expressions may take place according to the theoretical base of these models to conclude the layer formation, uniformity besides reaction reversibility, and favourability from kinetic- thermodynamic principles.

Coefficient of determination (R²) is a mean variation of data or a degree of proper or fitting as mostly used in kinetic and isotherm literatures. In adsorption investigations, experimental physical- chemical conditions and error sources are the main influenced factors, for example, at surface coverage (or inhibition efficiency) in corrosion treatments or adsorption capacity in pollution subject. Linearity variation will govern R² to predict adsorbate behaviour on adsorbent surface that is highly influenced by concentration, temperature, pH, type of measuring method, physical and chemical structures of the adsorbent and adsorbate, and error sources in each experiment.

المراجع

I. Manisalidis, E. Stavropoulou, A. Stavropoulops, and E. Berirtzoglou, “Environmental and health impacts of air pollution: a review”, Frontier Public Health, vol. 8, 2020. https://doi.org/10.3389/fpubh.2020.00014

M. Ghaedi, “Fundamental Processes and applications”, Serious book, Interface Science and Technology, vol. 33, Pages 2-713, Elsevier B.V., USA, 2021.

P. Cong and Y. Cheng, “Advances in geopolymer materials: a comprehensive review”, Journal of Traffic and Transportation Engineering, vol. 8, no. 3, pp. 283-314, 2021.

O. Lipiar and M. Mazumder, “Green Corrosion Inhibitors”, In Corrosion Inhibitors, A. Singh (Editor). IntechOpen, UK, 2019.

I. Sharma, “Bioremediation Techniques for Polluted Environment: Concept, Advantages, Limitations, and Prospects in Trace Metals in the Environment- New Approaches and Recent Advances”, M. Murillo-Tovar, H. Saldarriaga-Noreña, and A. Saeid (Editors), IntechOpen, UK, 2020.

K. Foo and B. Hameed, “Insight into the modelling of adsorption isotherm systems”, Chemical Engineering Journal, vol. 156, pp. 2-10, 2010.

G. Limousin, J. Gaudet, L. Charlet, S. Szenknect, V. Barthe, and M. Krimissa, “Sorption isotherm: a review on physical bases, modelling, and measurement”, Applied Geochemistry, vol. 22, no. 2. Pp. 249-275, 2007.

N. Ayawei, A. Ebelegi, and D. Wankasi, (2017). “Modelling and interpretation of adsorption isotherms”, Journal of Chemistry, Vol. 2017, Article ID 3039817, 2017. https://doi.org/10.1155/2017/3039817

H. Agbovi and L. Wilson, “Adsorption process in biopolymer systems: fundamentals to practical applications”, S. Kalia (Editor), in Natural polymer – based green adsorbents for water treatment, Elsevier, USA, 2021.

R. Krishna and J. van Baten, “How reliable is the adsorbed solution theory for the estimation of mixture separation selectivities in microporous crystalline adsorbents?”, ACS Omega 6 (23), pp. 15499-15513, 2021. https://doi.org/10.1021/acsomega.1c02136

E. D. Revellame, D. L. Fortela, W. Sharp, R. Hernandez, and M. E. Zappi, “Adsorption kinetic modelling using pseudo- first order and pseudo-second order rate laws: a review”, Cleaner Engineering and Technology, vol. 1, 100032, 2020. https://doi.org/10.1016/j.clet.2020.100032

N. A. Aviara. “Moisture sorption isotherms and isotherm model performance evaluation for food and agricultural products”, G. Kyzas and N. Lazaridis (Editors), IntechOpen, UK, 2020.

R. Mishra and K. Mohanty, “Kinetic analysis and pyrolysis behaviour of low – value waste lignocellulose biomass for its bioenergy potential using thermogravimetric analyser”, Materials Science for Energy Technologies, vol. 4, pp. 136-147, 2021. https://doi.org/10.1016/j.mset.2021.03.003

O. D. Agboola and N. U. Benson, “Physisorption and chemisorption mechanisms influencing Micro (Nano) Plastics-Organic chemical contaminants interactions: a review”, Frontiers in Environmental Science, vol. 9, 678574, 2021. https://doi.org/10.3389/fenvs.2021.678574

S. Busetty, “Environmental treatment technologies: Adsorption”, In C. Hussain (Editor), Handbook of Environmental Materials Management, Springer, Switzerland, 2019.

M. Benjelloun, Y. Miyah, G. Evrendilek, F. Zerrouq, and S. Lairini, “Recent advances in adsorption kinetic models: Their application to dye types”, Arabian Journal of Chemistry, vol. 14, no. 4, 103031, 2021. https://doi.org/10.1016/j.arabjc.2021.103031

J. Wang, Y. Wei, and Z. Ma, “Modified Dual-Site Langmuir Adsorption Equilibrium Models from A GCMC Molecular Simulation,” Applied Sciences, vol. 10, no. 4, p. 1311, Feb. 2020, doi: 10.3390/app10041311. [Online]. Available: http://dx.doi.org/10.3390/app10041311

[18] C. Tien, “Introduction to Adsorption: Basic, Analysis, and Applications”, Elsevier Inc., USA, 2019.

A. A. Inyinbor, F. A. Adekola, and G. Olatunji, “Kinetics, isotherms, and thermodynamic modelling of liquid phase adsorption of Rhodamine B dye onto Raphia hookerie fruit epicarp. Water Resources and Industry, vol. 15, pp. 14-27, 2016. https://doi.org/10.1016/j.wri.2016.06.001

V. Palomba and A. Frazzica, “Modeling of sorption for thermal energy storage”, Chapter 15, in Advances in Thermal Energy Storage Systems: Methods and Applications, L. Cabeza (Editor), 2nd Edition, A volume in Woodhead Publishing Series in Energy, Elsevier Ltd., USA, 2021.

M. Vigdorowitsch, A. Pchelintsey, L. Tsygankova, and E. Tanygina. (2021). “Freundlich isotherm: an adsorption model complete framework”, Applied Sciences, vol. 11, no. 17, 8078. https://doi.org/10.3390/app11178078

P. Sipos, “Searching for optimium adsorption curve for metal sorption on soils: comparison of various isotherm models fitted by different error functions”, SN Applied Sciences 3, Article number: 387, 2021. https://doi.org/10.1007/s42452-021-04383-0

L. Fu, J. Li, G. Wang, Y. Luan, and W. Dai, “Adsorption behaviour of organic pollutants on microplastics”, Ecotoxicology and Environmental Safety, vol. 217, 112207, 2021. https://doi.org/10.1016/j.ecoenv.2021.112207

I. Ivancev-Tumbas, L. Landwehrkamp, R. Hobby, M. Vernillo, and S. Panglisch. “Adsorption of organic pollutants from the equeous phase using graphite as a model adsorbent”, Adsorption Science & Technology, vol. 38(7-8), pp. 286-303, 2020. https://doi.org/10.1177/0263617420945847

L. Wu, X. Liu, G. Lv, R. Zhu, L. Tian, M. Liu, Y. Li, W. Rao, T. Liu, and L. Liao, “Study on the adsorption properties of methyl orange by natural one- dimensional nano-mineral material with different structures”, Scientific Reports, vol. 11, Article number 10640, 2021. https://doi.org/10.1038/s41598-021-90235-1

A. Singh, S. Sonal, R. Kumar, B. Mishra, “Adsorption of chlorhexidine digluconate on acid modified fly ash: kinetics, isotherms, and influencing factors”, Environmental Engineering Research, vol. 25, no. 2, pp. 205-211, 2020. DOI: https://doi.org/10.4491/eer.2018.412

W. Ebiduduna, O. Akeme, and T. Zinipere, “Comparison of various adsorption isotherm models for allium cepa as corrosion inhibitor on Austenitic stainless steel in sea water”. International Journal of Scientific & Technological Research, vol. 8, no. 8, pp. 961-964, 2019.

M. Adebayo, S. AkAande, A. Olounfemi, O. Ajayi, J. Orge, and E. Daniel, “Equilibrium and thermodynamic characteristics of the corrosion of mild steel using sweet prayer leaf extract in alkaline medium”, Progress in Chemical and Biochemical Research, vol. 4, no. 1, pp. 80-91, 2021. DOI: https://doi.org/10.22034/pcbr.2021.120449

S. Adejo, M. Ekwenchi, J. Ahile, J. Gbertyo, B. Ishua, and A. Akombor, “Modeling of adsorption isotherm for methanol leaf extract of Maihot esculentum as green corrosion inhibitor of corrosion of mild steel in HCl medium”, Journal of Corrosion Science and Engineering, vol. 17, pp. 1-13, 2014.

Z. Tao, Y. Li, Y. X. Peng, H. Su, L. Han, and G. Li, (2020). “Electrochemical studies of prothioconazole as a novel corrosion inhibitor for copper in acidic solutions”, RSC Advances, vol. 10, pp. 21517-21529, 2020. DOI: https://doi.org/10.1039/D0RA02919J