تحويل الحمأة الزيتية الخام العراقية الخطرة إلى كربون منشط ذو قيمة مضافة باستخدام تقنية تنشيط بهيدروكسيد البوتاسيوم

المؤلفون

  • عواد عيسى محمد Chemical Engineering Department, College of Engineering, University of Baghdad, Iraq
  • صبا عدنان غني Chemical Engineering Department, College of Engineering, Tikrit University, Iraq.
  • ودود طاهر محمد Chemical Engineering Department, College of Engineering, University of Baghdad, Iraq
  • محمود عبد الكريم عبد القادر Oil Products Distribution Company, (OPDC) Salahuldeen Branch, Tikrit, Ministry of Oil, Iraq
  • عمر عبد حبيب North Refineries Company (NRC), Ministry of Oil, Salahuldeen, Baiji, Iraq.

DOI:

https://doi.org/10.52716/jprs.v14i1.773

الكلمات المفتاحية:

Oily Sludge (OS), Activated Carbon (AC), Pyrolysis, KOH activation.

الملخص

يتم إنتاج كمية كبيرة من الحمأة الزيتية الخطرة سنويًا من قبل شركة مصافي الشمال. يهدف هذا العمل إلى دراسة مواصفات الحمأة الزيتية في صهاريج تخزين النفط الخام وتحويلها إلى كربون منشط عن طريق التحلل الحراري باستخدام هيدروكسيد البوتاسيوم. تم قياس وتحليل الخصائص الفيزيائية للكاربون المنشط المنتج. يتم إنتاج الكاربون المنشط عن طريق تفحيم الحمأة الزيتية إلى الفحم تحت جو من النتروجين بنسبة تشريب تبلغ 2:1KOH/char . تم تشخيص تركيبة المسامات في الكاربون المنتج و بنائية سطحه وكيمياء السطح باستخدام عدة اجهزة تشخيصية مثل (BET)، ومجهر المسح الإلكتروني(FESEM) ، ومطياف فورييه لتحويل الأشعة تحت الحمراء(FTIR). تظهر النتائج أن المساحة السطحية للكاربون المنشط المنتج كانت 350 م2/غم مع بنية مسامية. بناءً على النتائج، تشير المساحة السطحية التي تم الحصول عليها إلى أن الحمأة الزيتية كانت بمثابة مصدر لوقود خفيفة، وهو ما يساعد في إنتاج الغاز والوقود السائل بدلاً من الوقود الصلب.

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التنزيلات

منشور

2024-03-20

كيفية الاقتباس

(1)
Mohammed, A. E. .; Gheni, S. A.; Mohammed, W. T. .; Abdulqader, M. A. .; Habeeb, O. A. . تحويل الحمأة الزيتية الخام العراقية الخطرة إلى كربون منشط ذو قيمة مضافة باستخدام تقنية تنشيط بهيدروكسيد البوتاسيوم. Journal of Petroleum Research and Studies 2024, 14, 154-175.

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