Thermodynamic Modeling of Wax Deposition Phase Behavior for Reservoir Fluid in Southern Iraqi Oil Field
DOI:
https://doi.org/10.52716/jprs.v16i1.1023Abstract
Most reservoir fluids contain heavy paraffinic compounds that may precipitate as a solid or solid-like material called wax if the fluid is cooled down. Wax precipitation may cause operational problems when unprocessed well streams are transported in undersea pipelines, in which the temperature may fall to that of the surrounding seawater. Wax may deposit as a solid layer inside the pipeline. With continued transport, this layer will build up and eventually plug the pipeline if not mechanically removed. The need to proactively predict the temperature at which wax will precipitate leads to the development and application of thermodynamic models for such prediction. This study aims to develop a thermodynamic model to predict the wax deposition envelope (WDE), which gives a good idea of the temperature at which wax precipitation occurs. Using a live oil sample from southern Iraqi oilfield, this study used the Soave-Redlich-Kwong (SRK-EOS) model that can predict the specific conditions at which wax precipitation occurs as well as respond to the reservoir fluid. The SRK-EOS results in the Multiflash program were matched with the fluid and wax experimental data. The results pointed out that wax precipitation would happen in tandem with the same production scenario after the temperature dropped.
References
M. A. Theyab, "Wax deposition process: mechanisms, affecting factors and mitigation methods", Open Access J. Sci., vol. 2, no. 2, pp. 112-118, 2018. https://doi.org/10.15406/oajs.2018.02.00054.
N. N. Johnson-Achilike, and G. A. Chukwu, and J. Ajienka, "Thermodynamic Modelling for Mapping Wax Deposition Envelope for an Identified Niger Delta Oilfield", presented at SPE Nigeria Annual International Conference and Exhibition, Aug. 2015, p. SPE-178317, 2015. https://doi.org/10.2118/178317-MS.
R. C. Albagli, L. B. Souza, and A. O. Nieckele, "Reynolds number influence on wax deposition", presented at Offshore Technology Conference Brasil, Oct. 2017, p. D031S025R002, 2017. https://doi.org/10.4043/28053-MS.
J. I. Aguiar, A. A. Nerris, and A. Mahmoudkhani, "Can Paraffin Wax Deposit Above Wax Appearance Temperature? A Detailed Experimental Study", presented at SPE Annual Technical Conference and Exhibition, p. SPE-201297-MS, Oct. 2020. https://doi.org/10.2118/201297-MS.
D. Stratiev, I. Shishkova, R. Nikolova, T. Tsaneva, M. Mitkova, and D. Yordanov, "Investigation on precision of determination of SARA analysis of vacuum residual oils from different origin", Petroleum & Coal, vol. 58, no. 1, pp. 109-119, 2016.
P. Ilushin, K. Vyatkin, and A. Kozlov, "Development of a New Model for the Formation of Wax Deposits through the Passage of Crude Oil within the Well", Sustainability, vol. 15, no. 12, p. 9616, 2023. https://doi.org/10.3390/su15129616.
F. O. Ochieng, M. N. Kinyanjui, J. O. Abonyo, and P. R. Kiogora, "Mathematical Modeling of Wax Deposition in Field-Scale Crude Oil Pipeline Systems", Journal of Applied Mathematics, 2022. https://doi.org/10.1155/2022/2845221.
O. M. Akinyede, "Development of a Thermodynamic Model for Wax Precipitation in Produced Crude Oil—Case Study of Hydrocarbon Fluid from Niger-Delta, Nigeria", Ph.D. dissertation, African University of Science and Technology, Abuja, Nigeria, 2019.
A. A. Olajire, "Review of wax deposition in subsea oil pipeline systems and mitigation technologies in the petroleum industry", Chemical Engineering Journal Advances, vol. 6, p. 100104, 2021. https://doi.org/10.1016/j.ceja.2021.100104.
J. Wang, F. Zhou, L. Zhang, Y. Huang, E. Yao, L. Zhang, F. Wang, and F. Fan, "Experimental study of wax deposition pattern concerning deep condensate gas in Bozi block of Tarim Oilfield and its application", Thermochimica Acta, vol. 671, pp. 1-9, 2019. https://doi.org/10.1016/j.tca.2018.10.024.
M. K. Rogachev, T. N. Van, and A. N. Aleksandrov, "Technology for preventing the wax deposit formation in gas-lift wells at offshore oil and gas fields in Vietnam", Energies, vol. 14, no. 16, p. 5016, 2021. https://doi.org/10.3390/en14165016.
J. H. Gary, J. H. Handwerk, and M. J. Kaiser, "Petroleum Refining: Technology and Economics", 5th ed., CRC Press, 2007. https://doi.org/10.4324/9780203907924.
M. A. Ahmed, G. H. Abdul-Majeed, and A. K. Alhuraishawy, "Modeling of asphaltene precipitation using CPA-EOS for live oil in an Iraqi oil well", in AIP Conference Proceedings, vol. 2839, no. 1, p. 020038, AIP Publishing LLC, 2023. https://doi.org/10.1063/5.0167684.
S. M. H. Hashemi, K. Monfaredi, and B. Sedaee, "An inclusive consistency check procedure for quality control methods of the black oil laboratory data", Journal of Petroleum Exploration and Production Technology, vol. 10, pp. 2153-2173, 2020. https://doi.org/10.1007/s13202-020-00869-6
S. Rezaee, "Separation and Characterization of Crude Oils and Investigation of Their Wetting Properties on Rock Surfaces", Ph.D. dissertation, Rice University, 2019.
H. Yin, Y. Chen, X. You, Z. Chen, D. He, and H. Gong, "SARA Characterization and Comparison for the Ultra-Heavy Oil via Combined Analyses", Journal of Energy Resources Technology, vol. 145, no. 11, 2023. https://doi.org/10.1115/1.4062925.
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