A Review on Desulfurization of Kerosene: Current Practices and Future Innovation

Authors

  • Haider J. Ismaeel Chemical Engineering Department, College of Engineering, Tikrit University, Salah ad-Din, Iraq.
  • Safaa M. R. Ahmed Chemical Engineering Department, College of Engineering, Tikrit University, Salah ad-Din, Iraq.

DOI:

https://doi.org/10.52716/jprs.v16i3.1048

Keywords:

Desulfurization, Oscillatory Baffled Reactor (OBR), Kerosene, Petroleum refining.

Abstract

Kerosene desulfurization is one of the most pressing tasks for the petroleum sector because the amount of slfur emissions that affect air quality is more strictly controlled by legislation. This review addresses the growing scope and challenge of kerosene desulfurization technology by providing an integrative perspective on current practices and development trends. The perspectives presented in this paper aim to help improve the development of efficient and environmentally friendly solutions to meet changing social and industrial requirements. In this review, advanced desulfurization technologies are available for use in kerosene including hydrodesulfurization (HDS), oxidative desulfurization (ODS) and adsorption desulfurization methods to meet the permissible compliance level of the Global Fuel Standard (October 2023). HDS is very efficient and widely applied but there are a number of limitations to HDS such as high energy consumption and high maintenance cost as the refractory sulfur compound cannot be removed. This is because recent developments in utang technologies are of great interest as they may improve the degree of desulfurization at low environmental and economic costs. These include advanced catalyst designs, ionic liquids and bio-desulfurization techniques. The paper presents key aspects of new possibilities such as green chemistry application and hybrid setup of processes that utilize the advantages of several technologies to achieve better performance.

References

A. K. Dizaji, B. Mokhtarani, and H. R. Mortaheb, "Deep and fast oxidative desulfurization of fuels using graphene oxide-based phosphotungstic acid catalysts," Fuel, vol. 236, pp. 717-729, 2019, doi: https://doi.org/10.1016/j.fuel.2018.09.076.

C. Opara, A. Oyom, and M. Okonkwo, "Deodorization of kerosene using activated carbon as adsorbent," Greener Journal of Physical Sciences, vol. 3, no. 2, pp. 070-075, 2013.

L. Wu, G. Miao, X. Dai, L. Dong, Z. Li, and J. Xiao, "Ultra-deep desulfurization of real diesel using two-layer silica gels under mild conditions," Energy & Fuels, vol. 33, no. 8, pp. 7287-7296, 2019, doi: https://doi.org/10.1021/acs.energyfuels.9b01896.

M. Omidghane, M. Bartoli, J. Asomaning, L. Xia, M. Chae, and D. C. Bressler, "Pyrolysis of fatty acids derived from hydrolysis of brown grease with biosolids," Environmental Science and Pollution Research, vol. 27, pp. 26395-26405, 2020, doi: https://doi.org/10.1007/s11356-020-09041-3.

G. Daware, A. Kulkarni, and A. Rajput, "Desulphurization of diesel by using low cost adsorbent," International Journal of Innovative and Emerging Research in Engineering, vol. 2, no. 6, pp. 69-73, 2015.

S. A. Dharaskar, S. K. Deshmukh, K. D. Bhuyar, and K. L. Wasewar, "Ionic liquids:- As energy efficient solvent for the extractive desulfurization of liquid fuels," in Proc. 3rd Int. Conf. Chemical, Agricultural and Medical Sciences (CAMS-2015), 2015 Singapore, pp. 10-11, 2015.

M. Safa, B. Mokhtarani, H. R. Mortaheb, K. Tabar Heidar, A. Sharifi, and M. Mirzaei, "Oxidative desulfurization of diesel fuel using a Brønsted acidic ionic liquid supported on silica gel," Energy & Fuels, vol. 31, no. 9, pp. 10196-10205, 2017, doi: https://doi.org/10.1021/acs.energyfuels.6b03505.

A. Gruia, “Hydrotreating,” in Handbook of Petroleum Processing, D. S. J. Jones and P. R. Pujadó, Eds. Dordrecht, The Netherlands: Springer, pp. 321–354, 2006, doi: https://doi.org/10.1007/1-4020-2820-2_8.

S. Gooneh-Farahani and M. Anbia, "A review of advanced methods for ultra-deep desulfurization under mild conditions and the absence of hydrogen," Journal of Environmental Chemical Engineering, vol. 11, no. 1, Art. no. 108997, 2023, doi: https://doi.org/10.1016/j.jece.2022.108997.

G. Zhang, F. Yu, and R. Wang, "Research advances in oxidative desulfurization technologies for the production of low sulfur fuel oils," Petroleum & Coal, vol. 51, no. 3, pp. 196-207, 2009.

I. Shafiq, S. Shafique, P. Akhter, W. Yang, and M. Hussain, "Recent developments in alumina supported hydrodesulfurization catalysts for the production of sulfur-free refinery products: A technical review," Catalysis Reviews, vol. 64, no. 1, pp. 1-86, 2022, doi: https://doi.org/10.1080/01614940.2020.1780824.

P. F. Schmidt, Fuel Oil Manual, Industrial Press Inc., New York, NY, USA, 1985.

P. Jokuty, “Properties of crude oil and oil products (not just another pretty database),” in International Oil Spill Conference, vol. 2001, no. 2, pp. 975–981, American Petroleum Institute, 2001, doi: https://doi.org/10.7901/2169-3358-2001-2-975.

A. Haruna, Z. M. A. Merican, S. G. Musa, and S. Abubakar, "Sulfur removal technologies from fuel oil for safe and sustainable environment," Fuel, vol. 329, Art. no. 125370, 2022, doi: https://doi.org/10.1016/j.fuel.2022.125370.

B. Pawelec, R. M. Navarro, J. M. Campos-Martin, and J. L. Fierro, "Retracted article: Towards near zero-sulfur liquid fuels: a perspective review," Catalysis Science & Technology, vol. 1, no. 1, pp. 23-42, 2011, doi: https://doi.org/10.1039/c0cy00049c.

R. N. Colvile, E. J. Hutchinson, and R. F. Warren, " Chapter 6 The transport sector as a source of air pollution," Developments in Environmental Science, vol. 1, pp. 187-239, 2002, doi: https://doi.org/10.1016/S1474-8177(02)80009-2.

K. E. Jeong, T. W. Kim, J. W. Kim, H. J. Chae, C. U. Kim, Y. K. Park, and S. Y. Jeong, "Selective oxidation of refractory sulfur compounds for the production of low sulfur transportation fuel," Korean Journal of Chemical Engineering, vol. 30, pp. 509-517, 2013, doi: https://doi.org/10.1007/s11814-013-0025-8.

M. A. Betiha, A. M. Rabie, H. S. Ahmed, A. A. Abdelrahman, and M. F. El-Shahat, "Oxidative desulfurization using graphene and its composites for fuel containing thiophene and its derivatives: An update review," Egyptian journal of petroleum, vol. 27, no. 4, pp. 715-730, 2018, doi: https://doi.org/10.1016/j.ejpe.2017.10.006.

E. Syntyhaki and D. Karonis, "Oxidative and extractive desulfurization of petroleum middle distillates, using imidazole ionic liquids," Fuel Communications, vol. 7, Art. no. 100011, 2021, doi: https://doi.org/10.1016/j.jfueco.2021.100011.

J. I. Humadi, Y. S. Issa, D. Y. Aqar, M. A. Ahmed, H. H. Ali Alak, and I. M. Mujtaba, "Evaluation the performance of the tin (IV) oxide (SnO2) in the removal of sulfur compounds via oxidative-extractive desulfurization process for production an eco-friendly fuel," International Journal of Chemical Reactor Engineering, vol. 21, no. 6, pp. 727-741, 2023, doi: https://doi.org/10.1515/ijcre-2022-0046.

M. Saeed, A. Riaz, A. Intisar, M. Iqbal Zafar, H. Fatima, H. Howari, A. Alhodaib, and A. Waseem, "Synthesis, characterization and application of organoclays for adsorptive desulfurization of fuel oil," Scientific Reports, vol. 12, no. 1, Art. no. 7362, 2022, doi: https://doi.org/10.1038/s41598-022-11054-6.

I. Sh. Ali, O. Y. Thayee Al-Janabi, E. T. B. Al-Tikrity, and P. J. S. Foot, “Adsorptive desulfurization of model and real fuel via wire-, rod-, and flower-like Fe3O4@MnO2@activated carbon made from palm kernel shells as newly designed magnetic nanoadsorbents,” Fuel, vol. 340, Art. no. 127523, 2023, doi: https://doi.org/10.1016/j.fuel.2023.127523.

M. Yaseen, S. Ullah, W. Ahmad, S. Subhan, and F. Subhan, "Fabrication of Zn and Mn loaded activated carbon derived from corn cobs for the adsorptive desulfurization of model and real fuel oils," Fuel, vol. 284, Art. no. 119102, 2021, doi: https://doi.org/10.1016/j.fuel.2020.119102.

S. H. Ammar and S. A. Jaafar, "Adsorption kinetic and isotherms studies of thiophene removal from model fuel on activated carbon supported copper oxide," Iraqi Journal of Chemical and Petroleum Engineering, vol. 18, no. 2, pp. 83-93, 2017, doi: https://doi.org/10.31699/IJCPE.2017.2.7.

R. M. Mohamed and A. A. Ismail, "Mesoporous Ag2O/ZrO2 heterostructures as efficient photocatalyst for acceleration photocatalytic oxidative desulfurization of thiophene," Ceramics International, vol. 48, no. 9, pp. 12592-12600, 2022, doi: https://doi.org/10.1016/j.ceramint.2022.01.127.

N. Zhao, S. Li, X. Zhang, X. Huang, J. Wang, R. Gao, J. Zhao, and J. Wang, "Photocatalytic performances of Ag/ALa4Ti4O15 (A= Ca, Sr and Ba) on H2O2 oxidative desulfurization," Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 481, pp. 125-132, 2015, doi: https://doi.org/10.1016/j.colsurfa.2015.04.028.

K. M. Rahman, O. Amiri, S. S. Ahmed, S. J. Ismael, N. S. Rasul, K. A. Babakrb, M. Dadkhah, and M. A. Jamal, “Mechanism and kinetic of piezo-catalytic desulfurization of model and actual fuel samples over CexOy/SrO nanocomposite at room temperature,” Heliyon, vol. 10, no. 2, Art. no. e24707, 2024, doi: https://doi.org/10.1016/j.heliyon.2024.e24707.

A. S. Morshedy, H. R. Ali, A. A. Nada, A. M. Rabie, and H. H. El-Maghrabi, "Highly efficient Imprinted Polymer Nanocomposites for photocatalytic desulfurization of real diesel fuel," Environmental Technology & Innovation, vol. 21, Art. no. 101206, 2021, doi: https://doi.org/10.1016/j.eti.2020.101206.

Y. Ma, M. Zhang, M. Sun, D. Xie, N. Mominou, C. Jing, and L. Wang, "Ultra-deep photocatalytic desulfurization of dibenzothiophene over hollow Core-shell N-doped graphene nanospheres anchored bimetallic single atoms under visible light," Fuel, vol. 324, part A, Art. no. 124577, 2022, doi: https://doi.org/10.1016/j.fuel.2022.124577.

J. o. P. Sousa, R. P. Neves, S. F. Sousa, M. J. Ramos, and P. A. Fernandes, "Reaction mechanism and determinants for efficient catalysis by DszB, a key enzyme for crude oil bio-desulfurization," ACS Catalysis, vol. 10, no. 16, pp. 9545-9554, 2020, doi: https://doi.org/10.1021/acscatal.0c03122.

I. Geronimo, S. R. Nigam, and C. M. Payne, "Desulfination by 2′-hydroxybiphenyl-2-sulfinate desulfinase proceeds via electrophilic aromatic substitution by the cysteine-27 proton," Chemical Science, vol. 8, no. 7, pp. 5078-5086, 2017, doi: https://doi.org/10.1039/c7sc00496f.

N. Nakayama, T. Matsubara, T. Ohshiro, Y. Moroto, Y. Kawata, K. Koizumi, Y. Hirakawa, M. Suzuki, K. Maruhashi, Y. Izumi, and R. Kurane, "A novel enzyme, 2′-hydroxybiphenyl-2-sulfinate desulfinase (DszB), from a dibenzothiophene-desulfurizing bacterium Rhodococcus erythropolis KA2-5-1: gene overexpression and enzyme characterization," Biochimica et Biophysica Acta (BBA)-Proteins and Proteomics, vol. 1598, no. 1-2, pp. 122-130, 2002, doi: https://doi.org/10.1016/S0167-4838(02)00365-5.

F. Davoodi-Dehaghani, M. Vosoughi, and A. A. Ziaee, "Biodesulfurization of dibenzothiophene by a newly isolated Rhodococcus erythropolis strain," Bioresource technology, vol. 101, no. 3, pp. 1102-1105, 2010, doi: https://doi.org/10.1016/j.biortech.2009.08.058.

D. S. Aribike, A. A. Susu, S. C. U. Nwachukwu, and S. A. Kareem, "Biodesulfurization of kerosene by Desulfobacterium indolicum," Nature and Science, vol. 7, no. 1, pp. 28–35, 2009.

S. Baradaran and M. T. Sadeghi, "Desulfurization of non-hydrotreated kerosene using hydrodynamic cavitation assisted oxidative desulfurization (HCAOD) process," Journal of Environmental Chemical Engineering, vol. 8, no. 4, Art. no. 103832, 2020, doi: https://doi.org/10.1016/j.jece.2020.103832.

X. Ma, A. Zhou, and C. Song, "A novel method for oxidative desulfurization of liquid hydrocarbon fuels based on catalytic oxidation using molecular oxygen coupled with selective adsorption," Catalysis Today, vol. 123, no. 1-4, pp. 276-284, 2007, doi: https://doi.org/10.1016/j.cattod.2007.02.036.

Y. Shiraishi and T. Hirai, "Desulfurization of vacuum gas oil based on chemical oxidation followed by liquid− liquid extraction," Energy & Fuels, vol. 18, no. 1, pp. 37-40, 2004, doi: https://doi.org/10.1021/ef0301396.

M. Te, C. Fairbridge, and Z. Ring, "Oxidation reactivities of dibenzothiophenes in polyoxometalate/H2O2 and formic acid/H2O2 systems," Applied Catalysis A: General, vol. 219, no. 1-2, pp. 267-280, 2001, doi: https://doi.org/10.1016/S0926-860X(01)00699-8.

J. Xiao, L. Wu, Y. Wu, B. Liu, L. Dai, Z. Li, Q. Xia, and H. Xi, "Effect of gasoline composition on oxidative desulfurization using a phosphotungstic acid/activated carbon catalyst with hydrogen peroxide," Applied energy, vol. 113, pp. 78-85, 2014, doi: https://doi.org/10.1016/j.apenergy.2013.06.047.

H. Lü, S. Wang, C. Deng, W. Ren, and B. Guo, "Oxidative desulfurization of model diesel via dual activation by a protic ionic liquid," Journal of Hazardous materials, vol. 279, pp. 220-225, 2014, doi: https://doi.org/10.1016/j.jhazmat.2014.07.005.

L. Li, Y. Lu, H. Meng, and C. Li, "Lipophilicity of amphiphilic phosphotungstates matters in catalytic oxidative desulfurization of oil by H2O2," Fuel, vol. 253, pp. 802-810, 2019, doi: https://doi.org/10.1016/j.fuel.2019.05.082.

S. Otsuki, T. Nonaka, N. Takashima, W. Qian, A. Ishihara, T. Imai, and T. Kabe, "Oxidative desulfurization of light gas oil and vacuum gas oil by oxidation and solvent extraction," Energy & fuels, vol. 14, no. 6, pp. 1232-1239, 2000, doi: https://doi.org/10.1021/ef000096i.

V. Hulea, F. Fajula, and J. Bousquet, "Mild oxidation with H2O2 over Ti-containing molecular sieves—a very efficient method for removing aromatic sulfur compounds from fuels," Journal of Catalysis, vol. 198, no. 2, pp. 179-186, 2001, doi: https://doi.org/10.1006/jcat.2000.3149.

P. De Filippis and M. Scarsella, "Oxidative desulfurization: oxidation reactivity of sulfur compounds in different organic matrixes," Energy & Fuels, vol. 17, no. 6, pp. 1452-1455, 2003, doi: https://doi.org/10.1021/ef0202539.

J. M. Campos-Martin, M. C. Capel-Sanchez, and J. L. G. Fierro, "Highly efficient deep desulfurization of fuels by chemical oxidation," Green Chemistry, vol. 6, no. 11, pp. 557-562, 2004, doi: https://doi.org/10.1039/b409882j.

A. Ishihara, D. Wang, F. Dumeignil, H. Amano, E. W. Qian, and T. Kabe, "Oxidative desulfurization and denitrogenation of a light gas oil using an oxidation/adsorption continuous flow process," Applied Catalysis A: General, vol. 279, no. 1-2, pp. 279-287, 2005, doi: https://doi.org/10.1016/j.apcata.2004.10.037.

F. Yu and R. Wang, "Deep oxidative desulfurization of dibenzothiophene in simulated oil and real diesel using heteropolyanion-substituted hydrotalcite-like compounds as catalysts," Molecules, vol. 18, no. 11, pp. 13691-13704, 2013, doi: https://doi.org/10.3390/molecules181113691.

L. Sun, Z. Zhu, T. Su, W. Liao, D. Hao, Y. Chen, Y. Zhao, W. Ren, H. Ge, and H. Lü, "Novel acidic eutectic mixture as peroxidase mimetics for oxidative desulfurization of model diesel," Applied Catalysis B: Environmental, vol. 255, Art. no. 117747, 2019, doi: https://doi.org/10.1016/j.apcatb.2019.117747.

J. I. Humadi, S. A. Gheni, S. M. Ahmed, G. H. Abdullah, A. N. Phan, and A. P. Harvey, "Fast, non-extractive, and ultradeep desulfurization of diesel in an oscillatory baffled reactor," Process Safety and Environmental Protection, vol. 152, pp. 178-187, 2021, doi: https://doi.org/10.1016/j.psep.2021.05.028.

H. Mei, B. Mei, and T. F. Yen, "A new method for obtaining ultra-low sulfur diesel fuel via ultrasound assisted oxidative desulfurization☆," Fuel, vol. 82, no. 4, pp. 405-414, 2003, doi: https://doi.org/10.1016/S0016-2361(02)00318-6.

M. R. Jalali and M. A. Sobati, "Intensification of oxidative desulfurization of gas oil by ultrasound irradiation: Optimization using Box–Behnken design (BBD)," Applied Thermal Engineering, vol. 111, pp. 1158-1170, 2017, doi: https://doi.org/10.1016/j.applthermaleng.2016.10.015.

P. J. Gildo, N. Dugos, S. Roces, and M.-W. Wan, “Optimized ultrasound-assisted oxidative desulfurization process of simulated fuels over activated carbon-supported phosphotungstic acid,” in MATEC Web of Conferences, vol. 156, Art. no. 03045, 2018, doi: https://doi.org/10.1051/matecconf/201815603045.

R. Lange, J. Hanika, D. Stradiotto, R. R. Hudgins, and P. L. Silveston, "Investigations of periodically operated trickle-bed reactors," Chemical Engineering Science, vol. 49, no. 24, pp. 5615-5621, 1994, doi: https://doi.org/10.1016/0009-2509(94)00363-7.

B. Wilhite, M. McCready, and A. Varma, "Kinetics of phenylacetylene hydrogenation over Pt/γ-Al2O3 catalyst," Industrial & engineering chemistry research, vol. 41, no. 14, pp. 3345-3350, 2002, doi: https://doi.org/10.1021/ie0201112.

A. P. Harvey, M. R. Mackley, and T. Seliger, "Process intensification of biodiesel production using a continuous oscillatory flow reactor," Journal of Chemical Technology & Biotechnology: International Research in Process, Environmental & Clean Technology, vol. 78, no. 2‐3, pp. 338-341, 2003, doi: https://doi.org/10.1002/jctb.782.

A. Harvey, M. Mackley, and P. Stonestreet, "Operation and optimization of an oscillatory flow continuous reactor," Industrial & Engineering Chemistry Research, vol. 40, no. 23, pp. 5371-5377, 2001, doi: https://doi.org/10.1021/ie0011223.

N. Masngut, A. P. Harvey, and J. Ikwebe, "Potential uses of oscillatory baffled reactors for biofuel production," Biofuels, vol. 1, no. 4, pp. 605-619, 2010, doi: https://doi.org/10.4155/bfs.10.38.

D. Reay, C. Ramshaw, and A. Harvey, Process Intensification: Engineering for Efficiency, Sustainability and Flexibility, 2nd ed. Oxford, U.K.: Butterworth-Heinemann, 2013, doi: https://doi.org/10.1016/C2012-0-00253-0.

P. Stonestreet and P. Van Der Veeken, "The effects of oscillatory flow and bulk flow components on residence time distribution in baffled tube reactors," Chemical Engineering Research and Design, vol. 77, no. 8, pp. 671-684, 1999, doi: https://doi.org/10.1205/026387699526809.

H. Jian, and X. Ni, "A numerical study on the scale-up behaviour in oscillatory baffled columns, " Chemical Engineering Research and Design, vol. 83, no. 10, pp. 1163-1170, 2005, doi: https://doi.org/10.1205/cherd.03312.

K. Sutherland, L. Pakzad, and P. Fatehi, "Oscillatory power number, power density model, and effect of restriction size for a moving‐baffle oscillatory baffled column using CFD modelling," The Canadian Journal of Chemical Engineering, vol. 98, no. 5, pp. 1172-1190, 2020, doi: https://doi.org/10.1002/cjce.23713.

H. Jian and X. Ni, "A numerical study on the scale-up behaviour in oscillatory baffled columns," Chemical Engineering Research and Design, vol. 83, no. 10, pp. 1163-1170, 2005, doi: https://doi.org/10.1205/cherd.03312.

H. Q Hussein, S. M. Ali, B. A. Altabbakh, S. J. Hussein, Y. M. Ali, and S. K. Ibrahim, "Hydrodesulfurization and Hydrodearomatization of Kerosene over high metal loading Ni w/γ-Al2O3 Catalyst, " Journal of Petroleum Research and Studies, vol. 8, no. 4, pp. 28-46, Jul. 2021, doi: https://doi.org/10.52716/jprs.v8i4.261.

O. Levenspiel and W. K. Smith, "Notes on the diffusion-type model for the longitudinal mixing of fluids in flow," Chemical Engineering Science, vol. 6, no. 4-5, pp. 227-235, 1957, doi: https://doi.org/10.1016/0009-2509(57)85021-0.

M. Manninen, E. Gorshkova, K. Immonen, and X. W. Ni, "Evaluation of axial dispersion and mixing performance in oscillatory baffled reactors using CFD," Journal of Chemical Technology & Biotechnology, vol. 88, no. 4, pp. 553-562, 2013, doi: https://doi.org/10.1002/jctb.3979.

M. R. Mackley and X. Ni, "Mixing and dispersion in a baffled tube for steady laminar and pulsatile flow," Chemical Engineering Science, vol. 46, no. 12, pp. 3139-3151, 1991, doi: https://doi.org/10.1016/0009-2509(91)85017-R.

Z. Qi, H. Li, J. Chen, C. Ye, and T. Qiu, "Intensification of oxidative desulfurization by Zr (IV)-ionic liquid-HPW composite activating H2O2 system and mechanism insight," Fuel, vol. 322, Art. no. 124231, 2022, doi: https://doi.org/10.1016/j.fuel.2022.124231.

M. Ahmadian and M. Anbia, "Highly efficient oxidative desulfurization catalyzed by copper-based materials using hydrogen peroxide as oxidant," Fuel, vol. 324, Art. no. 124471, 2022, doi: https://doi.org/10.1016/j.fuel.2022.124471.

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2026-09-21

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(1)
Ismaeel, H. J.; Ahmed, S. M. R. A Review on Desulfurization of Kerosene: Current Practices and Future Innovation. Journal of Petroleum Research and Studies 2026, 16, 127-148.