Preparation and Characterization of High Surface Area Nanosilica from Iraqi Sand via Sol-Gel Technique

فردوس شاكر محمود; حسين قاسم حسين; زينب طالب عبد الوهاب

doi:10.52716/jprs.v12i4.645

المؤلفون

فردوس شاكر محمود الشركة العامة للصناعات الحديدية / وزارة الصناعة والمعادن، بغداد/ العراق
حسين قاسم حسين جامعة بغداد / كلية الهندسة / قسم الهندسة الكيمياوية
زينب طالب عبد الوهاب وزارة النفط/ مركز البحث والتطوير النفطي

DOI:

https://doi.org/10.52716/jprs.v12i4.645

الملخص

كشفت الدراسة الحالية عن عملية منخفضة التكلفة لاستخدام رمال الصحراء لتحضير السليكا النانوية باستخدام تقنية .Sol-Gel المواد الخام المستخدمة في هذا العمل هي هيدروكسيد الصوديوم، وحمض الهيدروكلوريك المركز، والمياه المقطرة، اضافة الى الرمل العراقي. تم تشخيص عينة نانوسيليكا بحيود الأشعة السينية (XRD)، والماسح المجهري الإلكتروني (SEM)، ومجهر القوة الذرية (AFM)، و قياس المساحة السطحية بطريقة BET، وكذلك التحليل الطيفي بتقنية (FTIR). اظهرت نتيجة XRD للنموذج المنتج بأن السليكا النانوية الناتجة ذات طور غير متبلور ولها قمة واسعة عند Θ2=22° – 22.5º. أظهر فحص SEM جسيمات السيليكا الكروية المتكتلة التي يتراوح قطرها بين 26.57 - 28.93 نانومتر.

بالإضافة إلى ذلك، كان متوسط حجم الجسيمات 76.35 نانومتر و بمدى أبعاد 40-110 نانومتر، وبلغت مساحة السطح 510.96 م²/غم. تم تضمين مجموعات silanol المرتبطة بالهيدروجين (Si – O – H) عند 3437.15 cm^-¹ ومجموعات siloxane (Si – O – Si)عند 1087.85 cm^-¹ في أطياف FTIR.

المراجع

L. N. Nwidee, “Nanoparticles for Enhanced Oil Recovery Processes,” Curtin University, 2017.

H. M. Hasen and B. A. Abdulmajeed, “Theoretical investigation of the density and the heat capacity of [EMIM][BF4] and its MWCNTs ionanofluids: Effect of temperature and MWCNTs concentration,” J. Phys. Conf. Ser., vol. 2114, no. 1, 2021, doi: 10.1088/1742-6596/2114/1/012036.

M. Thiruvengadam, G. Rajakumar, and I. M. Chung, “Nanotechnology: current uses and future applications in the food industry,” 3 Biotech, vol. 8, no. 1, pp. 1–13, 2018, doi: 10.1007/s13205-018-1104-7.

S. Mor, C. K. Manchanda, S. K. Kansal, and K. Ravindra, “Nanosilica extraction from processed agricultural residue using green technology,” J. Clean. Prod., vol. 143, pp. 1284–1290, 2017, doi: 10.1016/j.jclepro.2016.11.142.

A. Ateeq and K. Sukkar, “Characterization of Nanosilica and Comparing Its Effect on Crude Oils and Diesel Fuel,” J. Nat. Sci. Res., 2019, doi: 10.7176/jnsr/9-4-08.

J. D. Guzmán, C. A. Franco, and F. B. Cortés, “An Enhanced-Solvent Deasphalting Process: Effect of Inclusion of SiO₂ Nanoparticles in the Quality of Deasphalted Oil,” J. Nanomater., vol. 2017, pp. 1–14, 2017, doi: 10.1155/2017/9470230.

K. S. Budiasih, Z. Ikawati, Z. Marsha, A. Aris, and R. Chrismara, “Silica-nanoparticles in slow release supplement: Preparation and characterization,” J. Phys. Conf. Ser., vol. 1156, no. 1, 2019, doi: 10.1088/1742-6596/1156/1/012008.

F. D. M. Daud, M. H. Johari, A. H. A. Jamal, N. A. Z. Kahlib, and A. L. Hairin, “Preparation of nano-silica powder from silica sand via sol-precipitation method,” AIP Conf. Proc., vol. 2068, no. February, pp. 1–5, 2019, doi: 10.1063/1.5089301.

K. T. Shnaihej, S. F. Khaleel, and K. A. Sukkar, “Preparation of Nano Silica particles by laboratory from Iraqi sand and added it to concrete to improve hardness specifications,” J. Pet. Res. Stud., no. 24, pp. 36–58, 2019.

M. Y. Tamar-agha and A. A. A. Ibrahim, “the Silica Sand Deposits in the Western Desert of Iraq :,” no. 8, pp. 225–240, 2019.

A. H. Salem, “Preparation and characterization of nano silica and its application in rubber reinforcement,” University of Technology, 2015.

S. M. T. Al-Abboodi, E. J. A. Al-Shaibani, and E. A. Alrubai, “Preparation and Characterization of Nano silica Prepared by Different Precipitation Methods,” IOP Conf. Ser. Mater. Sci. Eng., vol. 978, no. 1, 2020, doi: 10.1088/1757-899X/978/1/012031.

C. K. Manchanda, R. Khaiwal, and S. Mor, “Application of sol–gel technique for preparation of nanosilica from coal powered thermal power plant fly ash,” J. Sol-Gel Sci. Technol., vol. 83, no. 3, pp. 574–581, 2017, doi: 10.1007/s10971-017-4440-x.

H. El-Didamony, E. El-Fadaly, A. A. Amer, and I. H. Abazeed, “Synthesis and characterization of low cost nanosilica from sodium silicate solution and their applications in ceramic engobes,” Bol. la Soc. Esp. Ceram. y Vidr., vol. 59, no. 1, pp. 31–43, 2020, doi: 10.1016/j.bsecv.2019.06.004.

R. R. Jalil and H. Q. Hussein, “The Influence of Nano Fluid Compared with Polyethylene Glycol and Surfactant on Wettability Alteration of Carbonate Rock,” IOP Conf. Ser. Mater. Sci. Eng., vol. 454, no. 1, 2018, doi: 10.1088/1757-899X/454/1/012046.

Radhip .N.R, Pradeep.N, A. A. M, and S.Varadharajaperumal, “Synthesis of Silica Nanoparticles from Malpe Beach Sand using Planetary Ball Mill Method,” J. Pure Appl. Ind. Phys., vol. 5, no. June, pp. 165–172, 2015.

S. Musić, N. Filipović-Vinceković, and L. Sekovanić, “Precipitation of amorphous SiO₂ particles and their properties,” Brazilian J. Chem. Eng., vol. 28, no. 1, pp. 89–94, 2011, doi: 10.1590/S0104-66322011000100011.

A. Wahyudi, A. Dessy, and Sariman, “Preparation of Nano Silica from Silica Sand Through Alkali Fusion,” Indones. Min. J., vol. 16, no. 3, pp. 149–153, 2013.

F. Shakir, H. Q. Hussein, and Z. T. Abdulwahhab, “Influence of Nanosilica on Solvent Deasphalting for Upgrading Iraqi Heavy Crude Oil,” Baghdad Sci. J., pp. 144–156, 2022, doi: http://dx.doi.org/10.21123/bsj.2022.6895.

R. Z. Farhan and S. E. Ebrahim, “Preparing nanosilica particles from rice husk using precipitation method,” Baghdad Sci. J., vol. 18, no. 3, pp. 494–500, 2021, doi: 10.21123/BSJ.2021.18.3.0494.

V. Jafari and A. Allahverdi, “Synthesis of nanosilica from silica fume using an acid-base precipitation technique and PVA as a nonionic surfactant,” J. Ultrafine Grained Nanostructured Mater., vol. 47, no. 2, pp. 105–112, 2014.

A. Jyoti, R. K. Singh, N. Kumar, A. K. Aman, and M. Kar, “‘Synthesis and properties of amorphous nanosilica from rice husk and its composites,” Mater. Sci. Eng. B Solid-State Mater. Adv. Technol., vol. 263, no. September 2020, p. 114871, 2021, doi: 10.1016/j.mseb.2020.114871.

R. Sharafudeen, J. M. Al-Hashim, M. O. Al-Harbi, A. I. Al-Ajwad, and A. A. Al-Waheed, “Preparation and Characterization of Precipitated Silica using Sodium Silicate Prepared from Saudi Arabian Desert Sand,” Silicon, vol. 9, no. 6, pp. 917–922, 2017, doi: 10.1007/s12633-016-9531-8.

N. J. Saleh, A. A. Abdulrahman, and Z. A. Yousif, “Characterization of Nano Silica prepared from Iraqi Rice,” J. Pet. Res. Stud., pp. 236–257.

R. R. Jalil, “Study the Influence of Nano Fluids on Carbonate Rocks Wettability for The Enhancement of Oil Recovery,” University of Baghdad, 2019.

H. X. Nguyen, N. T. T. Dao, H. T. T. Nguyen, and A. Q. T. Le, “Nanosilica synthesis from rice husk and application for soaking seeds,” IOP Conf. Ser. Earth Environ. Sci., vol. 266, no. 1, 2019, doi: 10.1088/1755-1315/266/1/012007.

R. Rajan, Y. Zakaria, S. Shamsuddin, and N. F. Nik Hassan, “Robust synthesis of mono-dispersed spherical silica nanoparticle from rice husk for high definition latent fingermark development,” Arab. J. Chem., vol. 13, no. 11, pp. 8119–8132, 2020, doi: 10.1016/j.arabjc.2020.09.042.

R. H. Alves, T. V. D. S. Reis, S. Rovani, and D. A. Fungaro, “Green Synthesis and Characterization of Biosilica Produced from Sugarcane Waste Ash,” J. Chem., vol. 2017, pp. 1–9, 2017, doi: 10.1155/2017/6129035.

E. A. Okoronkwo, P. E. Imoisili, S. A. Olubayode, and S. O. O. Olusunle, “Development of Silica Nanoparticle from Corn Cob Ash,” Adv. Nanoparticles, vol. 5, no. 02, pp. 135–139, 2016, doi: 10.4236/anp.2016.52015.